Reactions with Chlorine: Take 2 test tubes and add 1cm3 TTE (trichlorotrifluoroethane) and 1 cm3 chlorine water (a solution of chlorine in water) to each. Now add 1cm3 potassium bromide solution (KBr) to one tube and 1 cm3 potassium iodide solution (KI) to the other. Do you observe any color changes? Stopper the tubes with corks and shake them. What happens? Record your results.
Reactions with Bromine: Take 2 test tubes and add 1 cm3 TTE and 1 cm3 bromine water to each. Now add 1cm3 potassium chloride solution (KCl) to one tube and 1 cm3 potassium iodide solution (KI) to the other. Do you observe any color changes? Stopper the tubes with corks and shake them. What happens? Record your results.
Reactions with Iodine: Take 2 test tubes and add 1cm3 TTE and 1cm3 Iodine solution to each. Now add 1 cm3 potassium chloride solution (KCl) to one tube and 1 cm3 potassium bromide solution (KBr) to the other. Do you observe any color changes? Stopper the tubes with corks and shake them. What happens? Record your results.
Controls: Take three test tubes and add 1cm3 TTE to each. To the first, add 1cm3 chlorine water, to the second 1cm3 bromine water, and to the third 1 cm3 iodine solution. The TTE will tend to extract the chlorine, bromine, and iodine into it (the lower layer), and thus you will see the colors of theses three elements and be able to tell when they are present or absent in your experiments.
On the basis of your observations, complete and balance the following equations. If you observed no reactions, write N.R.
| KBr + Cl2 | ® |
| KI + Cl2 | ® |
| KCl + Br2 | ® |
| KI + Br2 | ® |
| KCl + I2 | ® |
| KBr + I2 | ® |
Questions: Which of these three halogens (Cl2, Br2, I2) is the most reactive? Which is the least reactive? Why do you suppose fluorine was not included in the experiment? Where would it have ranked? Why?