4 Mass, Volume, and Density
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Background

An old riddle asks "Which is heavier, a pound of feathers or a pound of lead?" The question is nonsensical, of course, since a pound of feathers and a pound of lead both weigh the same, one pound. Nevertheless, there is clearly something different about a small lead brick and a large bag of feathers, even though they weigh the same. The key to answering the riddle is understanding the relationship that exist between a substance's mass and the volume it occupies. This relationship is expressed by the physical property called density. Density is defined as the ratio of a substance's mass to the volume it occupies.

Density = mass of substance (g) / volume of substance (mL)

In this experiment, you will measure the mass and volume of several unknown materials. You will then use your data to explore the relationship between the mass and volume of the materials and to calculate their density.

Densities of Common Metals

Metal

Densuty (g/ml)

Cu

8.96

Pb

11.40

Fe

7.86

Zn

7.14

Sn

7.30

Al

2.70

Goals

Equipment

safety goggles

1 25-mL graduated cylinder

8 centigram balances / class

1 ruler

 
Safety

Procedure

Copy tables 4,1, 4.2, and 4.3 into your laboratory notebook. As you perform the experiment, record your data in Tables 4.1 and 4.2.

1. Determine the mass of two different unknown metal samples to the nearest 0.01 gram, using a centigram balance. Record masses in Tables 4.1 and 4.2.
2. Find the volume of each metal sample by water displacement. Fill a 25-mL graduated cylinder about half-full with water, measure the volume, and record as "volume of water alone" in Table 4.1. Tilt the graduated cylinder and carefully slide one of the metal samples down the side. Make sure the metal sample is completely submerged in the water. Measure the volume and record the measurements as "volume of water + metal" in Table 4.1.
3. Repeat step 2, using the other metal sample. Dry both samples and return them to your teacher.

Data Record

Table 1 Group Data - Density

 

Metal A

Metal B

Additional Metal Samples (Optional)

Mass (g)

 

 

 

Volume of water alone (ml)

 

 

 

Volume of water + Metal (ml)

 

 

 

Volume of metal (ml)

 

 

 

Density of metal (g/ml)

 

 

 

Idnetity of metal

 

 

 

Actual density of metal

 

 

 

Percent (%) deviation

 

 

 

Calculations:

 

Table 2 Class Data: Mass and Volume of Metal Samples

Lab Pair

mass A (g)

Volume A  (ml)

Mass B (g)

Volume B (ml)

Mass - added metal(g)

(Optional)

Volume - added metal (ml)

(Optional)

1

 

 

 

 

 

 

2

 

 

 

 

 

 

3

 

 

 

 

 

 

4

 

 

 

 

 

 

5

 

 

 

 

 

 

6

 

 

 

 

 

 

7

 

 

 

 

 

 

8

 

 

 

 

 

 

9

 

 

 

 

 

 

10

 

 

 

 

 

 

11

 

 

 

 

 

 

 

Data Analysis

Note, one page of graph paper is required for your laboratory report.

1. Compute the volume of each metal sample, using data from Table 4.1. Compute the
density of each metal sample, showing your work (including units), in Table 4.1. Remember, density = mass (g) / volume (mL).
2. Compute Table 4.2 by recording the mass and volume data collected by you and your classmates.
3. Using the class data, plot a graph of mass versus volume. Represent the plotted points for each metal with a different symbol. Draw a "best fit" straight line through each group of plotted points.
4. Determine the slope of each of the lines on your graph. Record the slope of each line and your method of calculation in Table 4.3. HINT: The general equation for a line is y=mx+b where m is the value for the slope and b is the value for the y-intercept. Pay attention to the units of the slope.

Table 4.3 Density Calculations Class Data  (slopes)

Metal A

Metal B

Additional Metal

y/x =

y/x =

 

 
Conclusions

1. What does the slope of the line for each metal represent? HINT: Look back at Table 4.1.
2. Looking at your graph, what does this experiment demonstrate about the density of a substance? What does it demonstrate about the densities of different substances?
3. Calculate the percent error in the density calculations for the two samples. (See Data Analysis, step 1.) Your teacher will provide the accepted value for the density of each metal.
percent error = |accepted value - experiment value|/ accepted value x 100 percent
4. Calculate the percent error in the values of density obtained from the slopes of the line in your graph.
5. Look back at the percent errors calculated in steps 3 and 4. Generally, the slope of the line will give a more accurate value for density than a single sample. Explain why this is usually true.
6. Can you identify a substance if you know its density? Explain your answer. Try to identify the metals used in this experiment by referring to tables of density.

Extensions

1. Do you think that determining the volumes for your metal samples by measuring their dimensions and calculating would be more or less accurate than determining these volumes by water displacement? Explain. Would measuring the dimensions of a solid always be possible? Explain.
2. How would you modify this experiment to determine the density of table sugar, wood chips, and milk?

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